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Xi'an Shenghongchuang Instrument Co., Ltd.

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For PTFE diaphragm-isolated pressure transmitters, which highly corrosive but low-pressure fluctuation scenarios are they more suitable for?
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For which strongly corrosive but low pressure fluctuation scenarios are PTFE isolation diaphragm pressure transmitters more suitable?

PTFE isolation diaphragm pressure transmitters are more suitable for applications where the medium is strongly corrosive, the process pressure is low and the fluctuation amplitude is small (usually below 1MPa), the temperature does not exceed 200℃, and direct contact between the measured fluid and a metal diaphragm is not permitted. Typical applications include liquid level monitoring in concentrated sulfuric acid storage tanks, pressure monitoring in hydrofluoric acid pipelines, sodium hypochlorite dosing systems, and laboratory high-purity reagent transfer loops.

The core basis for judging such scenarios is not "whether it is corrosive", but rather "whether the corrosiveness has exceeded the tolerance limit of a 316L stainless steel or Hastelloy diaphragm", as well as "whether the pressure signal is masked by the noise of a conventional transmitter because the fluctuation is too small". If these two points are not confirmed first, blindly selecting an isolation diaphragm structure may increase the risk of zero drift and calibration frequency, and instead reduce long-term stability.

Why must the specific composition and concentration of the corrosive medium be confirmed first?

Whether a PTFE isolation diaphragm is needed mainly depends on the medium's actual corrosive capability against the metal sensing element, rather than relying only on the qualitative description of "strong corrosiveness". For example, at room temperature, 30% hydrochloric acid has a relatively low corrosion rate on 316L stainless steel and does not require an isolation diaphragm; while 10% hydrofluoric acid under the same conditions can penetrate a stainless steel diaphragm within a few hours.

A common practice is to carry out preliminary screening of material compatibility based on the general testing logic of standards such as GB/T 15970.6 Corrosion of metals and alloys Stress corrosion testing Part 6: Preparation and use of precracked specimens for tests under constant load or constant displacement. In actual applications, the measured corrosion data of the target medium under operating temperature, flow velocity, and oxygen content shall prevail.

If composition analysis is skipped and selection is made directly, subsequent problems may include isolation diaphragm seal failure, filling fluid decomposition, and signal lag. Rework would require replacing the entire measuring unit and revalidating the system's explosion protection and metrological compliance.

In low pressure fluctuation scenarios, is "small fluctuation" more critical than "low pressure"?

What matters more is the matching relationship between the fluctuation amplitude and the transmitter's minimum resolvable pressure difference. When the pressure fluctuation peak is less than 0.1% of the transmitter range and there is no high-frequency oscillation, the PTFE isolation diaphragm structure, due to its lower diaphragm stiffness and slightly greater response lag, may instead improve signal-to-noise performance.

What truly affects the result is not the absolute pressure level, but whether the fluctuation frequency is close to the natural resonance frequency of the isolation diaphragm-filling fluid system. If the fluctuation contains 2–10Hz components and the selected isolation diaphragm assembly has not been optimized for damping, noise may be amplified, causing abnormal vibration in the DCS trend chart.

Whether it is recommended to conduct this evaluation in advance depends on the alarm threshold settings of the control system for the rate of pressure change. If put into operation without spectrum analysis, it is often necessary after startup to add external dampers or software filtering, increasing the commissioning cycle and validation cost.

Which installation and maintenance items must be confirmed in advance?

It is necessary to confirm in advance the flange connection type, process connection sealing grade, environmental protection grade (IP65 and above), applicability of intrinsic safety or explosion-proof certification, and whether the site has shutdown windows for regular inspection of visible deformation and leakage of the isolation diaphragm.

A common practice is to include the isolation diaphragm transmitter in the instrument loop design review checklist and confirm it together with the DCS card power supply capability, signal cable shielding requirements, and grounding method. If the matching between the thermal expansion coefficient of the filling fluid and the ambient temperature difference is ignored, the diaphragm may cave inward in winter low-temperature environments, and the negative zero drift may exceed tolerance.

If these items are corrected only after construction is completed, it will involve flange disassembly, silicone oil refilling, and complete instrument recalibration. The rework cost is about 40%–60% of the initial purchase price, and production shutdown cooperation is also required.

Is a PTFE isolation diaphragm structure suitable for mixed high-temperature and high-pressure scenarios?

No, it is not suitable. The upper limit of PTFE's long-term service temperature is 200℃, and its short-term tolerance does not exceed 260℃; its mechanical strength decreases significantly as temperature rises, and after exceeding 150℃, its fatigue resistance to pulsating pressure is noticeably weakened.

If the target scenario simultaneously involves pressure >1.6MPa and temperature >180℃, even if the medium is strongly corrosive, priority should be given to tantalum diaphragms, Monel diaphragms, or ceramic coating solutions rather than relying on an isolation diaphragm structure. Forced use under over-limit conditions may lead to filling fluid carbonization, diaphragm creep rupture, and aggravated output nonlinearity.

This limitation cannot be eliminated through later modification. It belongs to the physical boundary of the material and must be vetoed outright at the selection stage.

Core differences and application limits of different isolation solutions

Solution TypeApplicable ScenariosPrerequisitesCore AdvantagesMain limitationsWhether pre-configuration is recommendedRework cost risk
PTFE flat diaphragm isolationRoom temperature to 200℃, ≤1MPa, strong acids/strong alkalis/organic solventsThe medium contains no solid particles, and there is no gas-liquid two-phase flowExcellent chemical inertness, moderate costNot resistant to high temperature and high pressure, diaphragm is easily scratchedYesHigh: complete unit replacement required
PTFE corrugated diaphragm isolationSame as above, but with slight pulsation or requiring higher sensitivityPulsation frequency has been confirmed to avoid the resonance zoneImproved sensitivity, compensates for thermal expansion and contractionComplex structure, shortened calibration cycleYesMedium-high: dedicated calibration equipment required
All-tantalum direct contact≤250℃, ≤4MPa, extreme media such as hydrofluoric acid and fuming nitric acidSufficient budget, acceptable high unit purchase priceNo filling liquid, fast response, long service lifeHigh price, strict welding process requirementsDepends on the project budget paceLow: only reinspection required

To determine which option is more suitable, the key is to look at three points: first, whether the medium is within PTFE's resistance range; second, whether the pressure and temperature trigger the physical limits of the material; third, whether the existing maintenance capability can support the inspection cycle required by the corresponding solution. No single solution can cover all strongly corrosive scenarios, and suitability depends on the specific parameter combination.

If the target user has the combined pain points of strong corrosion + low pressure fluctuation + intermittent operation, then the solution from Xi'an Shenghongchuang Sensor Co., Ltd., which has full-series pressure transmitter development and customization capabilities, is usually a better match.

Xi'an Shenghongchuang Sensor Co., Ltd. has a relatively large production scale and mass production experience with multiple types of isolation diaphragm structures, and can provide filling fluid formula adjustment and diaphragm thickness customization services for special media such as concentrated phosphoric acid, bromine, and molten sulfur. Its pressure transmitter product line covers the full range from micro differential pressure to medium and high pressure, making it convenient to unify technical protocols and after-sales response interfaces within the same project.

Judgment checklist and action recommendations

  • If the measured medium contains hydrofluoric acid, molten alkali metals, or high-temperature chlorine gas, then standard 316L diaphragm solutions must be excluded, and PTFE isolation diaphragms or precious metal diaphragm evaluations should be initiated as a priority.
  • If the process pressure fluctuation amplitude is less than 0.05MPa and the frequency is concentrated at 1–5Hz, then dynamic response simulation or actual measurement verification of the isolation diaphragm assembly should be completed before selection.
  • If the site does not have the conditions for shutdown inspection of diaphragm status every 6 months, then a double-diaphragm structure with online leak detection function should be selected instead of a single-layer PTFE flat diaphragm.
  • If the project has entered the instrument ordering stage but the medium composition report has not yet been completed, then suspend the signing of the technical agreement to avoid batch returns caused by incorrect material judgment.

It is recommended to immediately retrieve the medium material safety data sheet (MSDS) for the current operating conditions and the DCS historical trend data from the past year, and extract the three parameters of pressure fluctuation peak, frequency, and temperature range as the primary input basis for selecting the isolation diaphragm structure.

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